Meaning
Hard optical ceramics and crystals possessing a cubic crystal structure provide robust protection for sensors operating in harsh environments. In military and industrial applications, spinel is used for multi-spectral windows because of its transmission from the ultraviolet to the infrared region. The material is manufactured either as a single crystal or as a polycrystalline ceramic through powder processing.
Its application is limited by the challenge of eliminating all sub-micron porosity during the sintering phase, which requires precise control over both the temperature profile and the applied pressure in hot isostatic presses.
Sintering Behavior
Polycrystalline powder must be compacted and heated to high temperatures under vacuum to promote grain growth and eliminate voids. Sintering of spinel is often done with a sintering aid like lithium fluoride to accelerate the densification process. This aid must be completely evaporated or distributed uniformly to prevent the formation of light-scattering secondary phases.
Optical Uniformity
Inhomogeneous distribution of grain sizes or residual sintering aids causes localized variations in the refractive index of the material. These variations lead to wavefront distortion and reduced inline transmission in the finished window. For high-resolution thermal imaging systems, spinel must be processed with extreme care to maintain optical homogeneity across the entire aperture.
Finished Blank
Transitioning to the polishing stage with poorly consolidated blanks results in a high scrap rate of the finished product. Unresolved internal pores in the spinel blanks are revealed as surface pits during grinding, which ruins the surface finish. Rigorous density and transmittance audits are performed on each batch to ensure that only high-quality blanks proceed to the final polishing steps.