Meaning
Molten material moves through a channel where temperatures vary between the center and the walls. Most injection processes involve non-isothermal polymer flow because the cold mold walls create a frozen layer while the core remains hot. This temperature gradient causes the viscosity of the material to change locally, affecting the pressure required to fill the cavity.
Rheological Shift
Viscosity is highly dependent on both temperature and shear rate during the filling stage. Within a non-isothermal polymer flow, the velocity profile deviates from a standard parabolic shape as the colder material near the walls resists movement. This behavior necessitates complex numerical solvers to predict the flow front position accurately.
Filling Behavior
Heat loss to the mold can lead to a premature freeze-off in thin sections. Analyzing non-isothermal polymer flow allows designers to size gates and runners to ensure the melt reaches the furthest extremities of the part. Higher injection speeds can sometimes offset heat loss through frictional heating.
Molecular Orientation
Internal stresses develop as the material solidifies under varying thermal conditions. Because non-isothermal polymer flow freezes the outer layers quickly, the polymer chains in the skin are often highly oriented in the direction of flow. This structural variation affects the mechanical properties and dimensional stability of the final product.