Meaning
Molding coefficients quantify the difference in material contraction along the direction of flow versus the transverse direction due to polymer chain alignment. The orientation shrinkage factor describes how molecular stretching during mold filling affects the dimensional stability of the cooled part. This factor applies to thin-walled injection molded components where high shear rates induce significant chain extension.
It is bounded by the gate location and the relaxation time of the specific polymer melt.
Molecular Alignment
Shear forces during the fill phase pull the polymer chains from their random coil state into highly aligned configurations. In terms of the orientation shrinkage factor, the degree of alignment is highest near the surface where cooling rates are fastest. Amorphous polymers preserve this oriented state more readily than semi-crystalline materials which undergo rapid reorganization during crystallization.
This freezing of oriented chains generates internal stresses that resolve as warpage after ejection.
Process Validation
Moving from a pilot mold to production tools necessitates a comprehensive study of the flow dynamics to prevent part distortion. Measuring the orientation shrinkage factor on prototype parts helps optimize the gate position and cavity pressure before machining the final production steel. Waiting to resolve shrinkage discrepancies until production runs start causes costly delay and tool rework.
A demonstrated shrinkage behavior must be achieved by adjusting melt temperature and pack pressure during the initial setup audits.
Anisotropic Variation
Flow path layout determines the distribution of oriented molecules throughout the mold cavity. Evaluating the orientation shrinkage factor reveals that contraction parallel to the flow is often several times greater than the perpendicular contraction.