Meaning
Dual phase stainless steels consisting of approximately equal parts austenite and ferrite offer resistance to chloride induced stress corrosion cracking. Tubing strings made from 22cr duplex provide high yield strength and better localized corrosion resistance than standard martensitic grades. The mixed microstructure inhibits the growth of cracks across grain boundaries.
This material finds frequent use in offshore production where seawater exposure is common.
Metallurgical Balance
Phase ratios must remain near fifty percent for each constituent to ensure performance. Manufacturing 22cr duplex requires precise control of nitrogen and chromium additions during the melting process. If the ferrite content becomes too high, the steel loses toughness and becomes susceptible to embrittlement.
Conversely, excessive austenite reduces the yield strength below the requirements for deep high pressure wells.
Yield Strength
Mechanical capability increases through cold work during the final stages of pipe production. Producers of 22cr duplex often use cold pilgering to reach the desired tensile properties.
Chemical Resistance
Pitting and crevice corrosion are mitigated by the presence of molybdenum and nitrogen in the alloy. While 22cr duplex handles carbon dioxide and chlorides effectively, its resistance to hydrogen sulfide is limited compared to higher alloy grades. Designers set the maximum allowable partial pressure of sour gas based on the operating temperature and the acidity of the produced water.
Failure to stay within these bounds leads to rapid cracking.